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Monday, December 2, 2019

Comparing ways to use CO2 ... other than putting bubbles in soda pop

CO2 is the
staff of life 
for our planet.

It's also waste gas 
most likely responsible 
for some global warming.

The UN's IPCC guesses
 "over 50%" of the warming.

Not very precise.

The correct answer is 
"No one knows".

The UN's IPCC says 
future global warming 
will be fast, and dangerous.

They have been 
saying that 
since 1988.

I stopped 
listening 
in 1989.

Global warming 
in the last 79 years 
of adding CO2 
to the atmosphere, 
since 1940, 
has been intermittent, 
mild, harmless, and 
mainly affected cold, 
dry areas, that actually 
enjoy warming.

So I have no agreement 
with the IPCC, because 
they live in a climate
fantasyland  -- making 
scary predictions 
of a future climate, 
that have been wrong 
since 1988.

I live in realityland -- 
observing and reporting 
actual climate change, 
never wasting your time 
with "It will be different 
in the future" fairy tales.

I favor more CO2 
in the atmosphere, 
to accelerate plant 
growth, which will 
better support 
healthy lives 
on this planet.

That statement 
is based on over 
3,000 scientific 
studies the IPCC 
could not care 
less about.

They are too busy
falsely demonizing CO2, 
a self serving strategy 
to make themselves 
appear to be relevant.



 “CO2 utilization” 
is an industrial process 
that makes an economically 
valuable product using CO2 
at concentrations above 
atmospheric levels. 

CO2 is transformed 
into materials, chemicals 
or fuels, using chemical 
reactions.

Or CO2 is used directly 
in processes such as 
enhanced oil recovery.


Using CO2 to make 
a valuable product 
would be good news.

CO2 utilization does not 
necessarily mean it would 
reduce global warming.

Not if the CO2 utilization 
required a fossil fuel 
energy-intensive process, 
NOT using nuclear, hydro, 
solar or wind power.

Two general types of
CO2 Utilization:
(A)
industrial processes
involve involve pulling 
CO2 out of the air — 
from exhaust gases 
of industrial facilities 
(aka "carbon capture"), 
or out of 
the ambient air, 
via direct air 
capture (DAC) , 
concentrating it, 
and using it as
an industrial 
feedstock.

(B)
Natural ways of gathering 
more CO2, ranging from 
planting more forests, 
to sequestering more 
carbon in the soil.




Lower Cost 
Technologies,
with high potential:

CO2-enhanced oil recovery (EOR)
Enhanced oil recovery means 
CO2 is injected in spent wells 
to squeeze out more oil and gas. 

Normally, operators try to 
maximize the oil and CO2 
recovered from the well. 

But EOR could be operated 
so more CO2 is injected, 
and permanently stored 
underground, than the CO2 
later released as people later 
burn the gasoline and 
natural gas from the wells. 

The cost should be low, 
but burning the gasoline 
and natural gas later
offsets much of the 
potential.




Concrete building materials
These are close to 
cost-competitive 
and have great potential. 

Concrete is a mix 
of cement, water, 
and aggregates. 

Cement is 
a fine powder. 

When activated 
by the water, 
it binds the 
aggregates
into a rigid mix. 

Aggregates can be made 
by converting gaseous CO2 
into solid mineral carbonates
 like calcium carbonate 
            (CaCO3), 
a process known as 
“CO2 mineralization.”

CO2 can also be 
substituted for water 
in “curing” concrete 
during its mixing, 
actually making 
the resulting concrete 
stronger, in addition 
to saving a lot of water.

Cement can be phased out 
in favor of new binding agents 
that absorb and mineralize CO2. 

The production process 
for cement and lime 
involves chemical reactions 
(not fossil fuel combustion) 
that release CO2. 

Scientists are working on 
that process releasing 
a purer CO2 that can 
be captured, then used 
as a CO2-mineralizing 
bonding agent, mixed 
with CO2-based aggregates. 

The resulting building 
materials would 
semi-permanently 
store carbon (CO2).

Some of these 
technologies are known,
relatively low energy, 
and could sequester 
a lot of carbon in concrete 
for a long period of time 
-- although concrete 
does not last forever.



CO2 chemicals
and other materials
Reducing CO2 
to its components 
using catalysts and 
chemical reactions 
is used to make methanol, 
urea (fertilizer) and
polymers (durable parts 
in buildings or cars).

Polymers, urea, 
and methanol 
are already 
cost-competitive, 
but their potential 
for CO2 use is small.

CO2 can also be be made 
into high-performance 
carbon composites, 
carbon fiber, and 
graphene, that could 
substitute for some uses 
of other materials. 

Such as metals 
and concrete.

A team at C2CNT 
is transforming CO2 
into carbon nanotubes, 
stronger than steel 
and highly conductive. 

They are already used 
in the Boeing Dreamliner 
and some sports cars. 

Think of substituting
light weight carbon nanotubes 
for copper in electricity wiring. 

Unfortunately this is 
still too expensive 
for almost all 
potential
applications.

Steel making 
is said to cause 
7% to 9% of global 
CO2 emissions 
from using fossil 
fuels in the process. 

Carbon-based materials 
substituted for steel 
could mean billions 
of tons of reduced 
CO2 emissions, and 
near permanent 
carbon sequestration.




Bioenergy with 
carbon capture 
and storage 
      (BECCS)
The operator 
captures CO2 
by growing trees, 
produces electricity 
through bioenergy 
and sequesters 
the resulting 
CO2 emissions. 

Moderate cost, 
but the potential 
for CO2 use is small.




Biochar
Biochar is plant material
that has been burnt at 
high temperatures 
under low oxygen levels. 

Biochar applied to 
agricultural soils 
has the potential 
to increase crop 
yields by 10%. 

Moderate cost, 
but very hard to make 
a consistent product, 
and the potential 
for CO2 use is small.




Soil carbon sequestration
Land management techniques 
to store CO2 in the soil 
and also enhance 
agricultural yields. 

Low to moderate cost, 
but the potential 
for CO2 use is small.




Forestry
Timber from both new 
and existing forests
used for building 
structures, 
displacing 
cement, brick
and steel use. 

The CO2 is then stored 
in the wood buildings 
for a long time. 

Inexpensive, but the 
potential for CO2 use 
is small, unless used for
more structures than
just single family homes.




High Cost Technologies:
CO2 fuels
Gasoline, 
diesel, 
and jet fuel 
are made 
by refining 
hydrocarbons 
drilled from 
underground. 

"Synthetic fuels" 
can be made 
with carbon 
from the air 
instead.

There are many 
different processes, 
and synthetic fuels 
can substitute 
for any liquid fuel.

They are a mix 
of a carbon-based 
molecule (usually CO2), 
hydrogen, and energy. 

If the CO2 comes 
from the ambient air, 
the electricity comes 
rom renewables, 
and the hydrogen 
comes from
solar-powered 
electrolysis
 (which pulls hydrogen 
directly out of water), 
the resulting fuel 
is extremely 
low carbon.

Carbon-neutral 
liquid fuels 
are a huge 
potential 
market 
for CO2. 

But it takes a lot of energy 
to electrolyze hydrogen 
and it takes even more 
to pry CO2 apart.

Extremely cheap 
renewable energy 
would make synthetic 
fuels work -- perhaps 
dedicated to the 
synthetic fuel facility.

Cheap renewables 
do not exist today.

Carbon-neutral liquid fuels 
also don’t remove CO2 
from the atmosphere.

They "recycle" CO2 once, 
and then put it back 
into the atmosphere 
when the synthetics 
are burned.




Microalgae 
-- experimental
Using microalgae 
to fix CO2, 
then processing 
the biomass 
to make products, 
such as fuels and 
high-value chemicals.

This has been 
researched for 
many years. 

High potential cost, 
and very low use of CO2




Enhanced weathering 
-- experimental
Crushing rocks, 
such as basalt, 
and spreading them
on land can result in the 
accelerated formation 
of stable carbonate 
from atmospheric CO2. 

Doing this on agricultural 
lands should result 
in higher yields.

But it is just 
another
interesting idea 
at this time.